Synthesis of the C59N+ carbocation. A monomeric azafullerene isoelectronic to C60

Kim KC, Hauke F, Hirsch A, Boyd P, Carter E, Armstrong R, Lay P, Reed C (2003)

Publication Language: English

Publication Type: Journal article, Original article

Publication year: 2003

Journal

Journal of the American Chemical Society American Chemical Society

Original Authors: Kim K.-C., Hauke F., Hirsch A., Boyd P.D.W., Carter E., Armstrong R.S., Lay P.A., Reed C.A.

Publisher: American Chemical Society

Book Volume: 125

Pages Range: 4024-4025

Journal Issue: 14

DOI: 10.1021/ja034014r

Abstract

A heterofullerene isoelectronic to C is reported. The azafullerenium cation CN can be isolated in good yield as a carborane salt via the two-electron oxidation of the C-C bond of (CN) dimer. [CN][Ag(CBHCl)] has been characterized by electronic, IR, Raman, and C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography. Copyright © 2003 American Chemical Society.

Authors with CRIS profile

Frank Hauke Zentralinstitut für Neue Materialien und Prozesstechnik Andreas Hirsch Lehrstuhl für Organische Chemie II

Involved external institutions

University of California Los Angeles (UCLA) US United States (USA) (US) University of Auckland NZ New Zealand (NZ)

How to cite

APA:

Kim, K.-C., Hauke, F., Hirsch, A., Boyd, P., Carter, E., Armstrong, R.,... Reed, C. (2003). Synthesis of the C59N+ carbocation. A monomeric azafullerene isoelectronic to C60. Journal of the American Chemical Society, 125(14), 4024-4025. https://dx.doi.org/10.1021/ja034014r

MLA:

Kim, Kee-Chan, et al. "Synthesis of the C59N+ carbocation. A monomeric azafullerene isoelectronic to C60." Journal of the American Chemical Society 125.14 (2003): 4024-4025.

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