Selective polycarboxylation of semiconducting single-walled carbon nanotubes by reductive sidewall functionalization

Gebhardt B, Hof F, Backes C, Müller M, Plocke T, Maultzsch J, Thomsen C, Hauke F, Hirsch A (2011)


Publication Language: English

Publication Type: Journal article, Original article

Publication year: 2011

Journal

Original Authors: Gebhardt B., Hof F., Backes C., Müller M., Plocke T., Maultzsch J., Thomsen C., Hauke F., Hirsch A.

Publisher: American Chemical Society

Book Volume: 133

Pages Range: 19459-19473

Journal Issue: 48

DOI: 10.1021/ja206818n

Abstract

The efficient and controllable synthesis, the detailed characterization, and the chemical postfunctionalization of polycarboxylated single-walled carbon nanotubes SWCNT(COOH) are reported. This innovative covalent sidewall functionalization method is characterized by (a) the preservation of the integrity of the entire σ-framework of SWCNTs; (b) the possibility of achieving very high degrees of addition; (c) control of the functionalization degrees by the variation of the reaction conditions (reaction time, ultrasonic treatment, pressure); (d) the identification of conditions for the selective functionalization of semiconducting carbon nanotubes, leaving unfunctionalized metallic tubes behind; (e) the proof that the introduced carboxylic acid functionalities can serve as versatile anchor points for the coupling to functional molecules; and (f) the application of a subsequent thermal degradation step of the functionalized semiconducting tubes leaving behind intact metallic SWCNTs. Functional derivatives have been characterized in detail by means of Raman, UV-vis/nIR, IR, and fluorescence spectroscopy as well as by thermogravimetric analysis combined with mass spectrometry, atomic force microscopy, and zeta-potential measurements. © 2011 American Chemical Society.

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APA:

Gebhardt, B., Hof, F., Backes, C., Müller, M., Plocke, T., Maultzsch, J.,... Hirsch, A. (2011). Selective polycarboxylation of semiconducting single-walled carbon nanotubes by reductive sidewall functionalization. Journal of the American Chemical Society, 133(48), 19459-19473. https://doi.org/10.1021/ja206818n

MLA:

Gebhardt, Benjamin, et al. "Selective polycarboxylation of semiconducting single-walled carbon nanotubes by reductive sidewall functionalization." Journal of the American Chemical Society 133.48 (2011): 19459-19473.

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