Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand
Maruyama M, Imoto K, König M, Guldi DM, Ohkoshi SI, Nakamura E, Matsuo Y (2013)
Publication Type: Journal article, Original article
Publication year: 2013
Journal
Original Authors: Maruyama M., Imoto K., König M., Guldi D.M., Ohkoshi S.-I., Nakamura E., Matsuo Y.
Publisher: American Chemical Society
Book Volume: 135
Pages Range: 10914-10917
Journal Issue: 30
DOI: 10.1021/ja405045t
Abstract
A cobalt-sulfur cluster CoS with molecular formula of (CAr)-CoSBu-(CAr) (Ar = 4- BuCH) was selectively synthesized from a pentaaryl[60]fullerene cobalt trisulfide complex, (η-C Ar)CoS. The bowl-shaped steric templating fullerene ligand, as well as the metastable cobalt trisulfide moiety, played important roles in the exclusive cluster formation. X-ray crystallography, as well as electrochemical, time-resolved photophysical, and magnetic, measurements revealed a mixed-valence cluster with six cobalt(III) and two high-spin cobalt(II) centers showing reversible redox behavior and photoinduced charge separation. © 2013 American Chemical Society.
Authors with CRIS profile
Matthias König
Lehrstuhl für Physikalische Chemie I
Dirk Michael Guldi
Lehrstuhl für Physikalische Chemie I
Involved external institutions
Japan (JP)How to cite
APA:
Maruyama, M., Imoto, K., König, M., Guldi, D.M., Ohkoshi, S.-I., Nakamura, E., & Matsuo, Y. (2013). Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand. Journal of the American Chemical Society, 135(30), 10914-10917. https://dx.doi.org/10.1021/ja405045t
MLA:
Maruyama, Masashi, et al. "Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand." Journal of the American Chemical Society 135.30 (2013): 10914-10917.
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