Krokos E, Schubert C, Spaenig F, Ruppert M, Hirsch A, Guldi DM (2012)
Publication Type: Journal article, Original article
Publication year: 2012
Original Authors: Krokos E., Schubert C., Spänig F., Ruppert M., Hirsch A., Guldi D.M.
Publisher: Wiley-VCH Verlag
Book Volume: 7
Pages Range: 1451-1459
Journal Issue: 6
The physicochemical characterization, that is, ground and excited state, of a new series of dendronized porphyrin/fullerene electron donor-acceptor conjugates in nonaqueous and aqueous environments is reported. In contrast to previous work, we detail the charge-separation and charge-recombination dynamics in zinc and copper metalloporphyrins as a function of first- and second-generation dendrons as well as a function of ortho, meta, and para substitution. Both have an appreciable impact on the microenvironments of the redox-active constituents, namely the porphyrins and the fullerenes. As a matter of fact, the resulting charge-transfer dynamics were considerably impacted by the interplay between the associated forces that reach from dendron-induced shielding to dipole-charge interactions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
APA:
Krokos, E., Schubert, C., Spaenig, F., Ruppert, M., Hirsch, A., & Guldi, D.M. (2012). Dendronized fullerene-porphyrin conjugates in ortho, meta, and para positions: A charge-transfer assay. Chemistry-An Asian Journal, 7(6), 1451-1459. https://doi.org/10.1002/asia.201200068
MLA:
Krokos, Evangelos, et al. "Dendronized fullerene-porphyrin conjugates in ortho, meta, and para positions: A charge-transfer assay." Chemistry-An Asian Journal 7.6 (2012): 1451-1459.
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