Time-resolved fluorescence spectroscopy of helically distorted aromatic systems.
Lanig H, Hof M, Bringmann G, Schneider F (1997)
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 1997
Journal
Publisher: ELSEVIER SCIENCE BV
Book Volume: 272
Pages Range: 478-483
Journal Issue: 5-6
DOI: 10.1016/S0009-2614(97)00540-X
Abstract
The fluorescence deactivation of several lactones and phenanthrene derivatives has been investigated by stationary and time-resolved fluorescence spectroscopy. Due to steric repulsions, these molecules are helically twisted around a central axis. Surprisingly, they show a negative temperature dependence of the natural fluorescence constant k(fo)=Phi(f)k(f). Considering both electronic and structural contributions we propose that the strain within the fluorescing molecules can be qualitatively described using the observed temperature dependence of k(fo). The larger this negative temperature dependence, the larger is the internal motion barrier in the molecules. (C) 1997 Published by Elsevier Science B.V.
Authors with CRIS profile
Involved external institutions
Academy of Sciences of the Czech Republic (ASCR) / Akademie věd České republiky (AVČR)
Czech Republic (CZ)
Julius-Maximilians-Universität Würzburg
Germany (DE)
Czech Republic (CZ)
Julius-Maximilians-Universität Würzburg
Germany (DE)
How to cite
APA:
Lanig, H., Hof, M., Bringmann, G., & Schneider, F. (1997). Time-resolved fluorescence spectroscopy of helically distorted aromatic systems. Chemical Physics Letters, 272(5-6), 478-483. https://dx.doi.org/10.1016/S0009-2614(97)00540-X
MLA:
Lanig, Harald, et al. "Time-resolved fluorescence spectroscopy of helically distorted aromatic systems." Chemical Physics Letters 272.5-6 (1997): 478-483.
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