Spectroscopic studies on inclusion properties of fullerenocalix[4]arene conjugates with metal ions

Luo C, Guldi DM, Soi A, Hirsch A (2005)


Publication Type: Journal article, Original article

Publication year: 2005

Journal

Original Authors: Luo C., Guldi D.M., Soi A., Hirsch A.

Publisher: American Chemical Society

Book Volume: 109

Pages Range: 2755-2759

Journal Issue: 12

DOI: 10.1021/jp044845z

Abstract

Metal-chelating properties - in the ground and excited states - of fullerenocalix[4]arenes containing two malonamide substituents at the upper rim and four alkyl ester chains at the lower rim have been studied by means of steady-state absorption, fluorescence spectroscopy, and time-resolved transient absorption spectra. In particular, the influence that Ag enforces on the fullerene electronic spectra is due to direct interactions between Ag and the surface of C . The effects stemming from Na , Mg , and Ba , on the other hand, are indirect and are introduced through chelating the metal ions to the calix[4]arene moiety. They strongly depend on the molecular structure of the fullerenocalix[4]arenes. No spectroscopic evidence was obtained for any influence caused by Mn , although the malonamide groups provide good chelating ability even for this transition metal ion. © 2005 American Chemical Society.

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How to cite

APA:

Luo, C., Guldi, D.M., Soi, A., & Hirsch, A. (2005). Spectroscopic studies on inclusion properties of fullerenocalix[4]arene conjugates with metal ions. Journal of Physical Chemistry A, 109(12), 2755-2759. https://dx.doi.org/10.1021/jp044845z

MLA:

Luo, Chuping, et al. "Spectroscopic studies on inclusion properties of fullerenocalix[4]arene conjugates with metal ions." Journal of Physical Chemistry A 109.12 (2005): 2755-2759.

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