Metathesis in pure water mediated by supramolecular additives

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autor(en): Brendgen T, Fahlbusch T, Frank M, Schühle DT, Seßler M, Schatz J
Zeitschrift: Advanced Synthesis & Catalysis
Verlag: Wiley-VCH Verlag
Jahr der Veröffentlichung: 2009
Band: 351
Heftnummer: 3
Seitenbereich: 303-307
ISSN: 1615-4150


Abstract


Supramolecular, water-soluble additives based on calix[n] arenes exhibit a beneficial influence on the ring-closing and cross metathesis of non-polar substrates in pure aqueous medium using standard Grubbs-II and Hoveyda-II catalysts. The catalytic activity observed in water is virtually the same as that in pure methanol. Quantitative yields of metathesis product can be achieved under mild aerobic conditions in/on water by (micro)solubilization of both the catalyst and starting materials by the macrocycles. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.



FAU-Autoren / FAU-Herausgeber

Schatz, Jürgen Prof. Dr.
Professur für Organische Chemie
Seßler, Miriam
Graduiertenzentrum der FAU


Zitierweisen

APA:
Brendgen, T., Fahlbusch, T., Frank, M., Schühle, D.T., Seßler, M., & Schatz, J. (2009). Metathesis in pure water mediated by supramolecular additives. Advanced Synthesis & Catalysis, 351(3), 303-307. https://dx.doi.org/10.1002/adsc.200800637

MLA:
Brendgen, Thomas, et al. "Metathesis in pure water mediated by supramolecular additives." Advanced Synthesis & Catalysis 351.3 (2009): 303-307.

BibTeX: 

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