Chelate electronic properties control the redox behaviour and superoxide reactivity of seven-coordinate manganese(II) complexes

Liu G, Dürr KL, Puchta R, Heinemann FW, van Eldik R, Ivanovic-Burmazovic I (2009)

Publication Type: Journal article, Original article

Publication year: 2009

Journal

Original Authors: Liu G., Dürr K., Puchta R., Heinemann F., Van Eldik R., Ivanović-Burmazović I.

Publisher: Royal Society of Chemistry

Book Volume: null

Pages Range: 6292-6295

Journal Issue: 32

DOI: 10.1039/b906100m

Abstract

We have synthesized and characterized two Mn(II) seven-coordinate complexes with N5 pentadentate ligands, which contain hydrazone and hydrazide groups respectively. We have shown that insertion of hydrazido (amido) groups into the ligand sphere increases the negative charge of the chelate, without changing a donor atom set and coordination geometry, and radically modulate a redox activity of seven-coordinate manganese complexes, which is important for the function of manganese as a superoxide dismutase catalytic center. © 2009 The Royal Society of Chemistry.

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How to cite

APA:

Liu, G., Dürr, K.L., Puchta, R., Heinemann, F.W., van Eldik, R., & Ivanovic-Burmazovic, I. (2009). Chelate electronic properties control the redox behaviour and superoxide reactivity of seven-coordinate manganese(II) complexes. Dalton Transactions, null(32), 6292-6295. https://dx.doi.org/10.1039/b906100m

MLA:

Liu, Gaofeng, et al. "Chelate electronic properties control the redox behaviour and superoxide reactivity of seven-coordinate manganese(II) complexes." Dalton Transactions null.32 (2009): 6292-6295.

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