Peters L, Hübner E, Haas T, Heinemann FW, Burzlaff N (2009)
Publication Type: Journal article, Original article
Publication year: 2009
Original Authors: Peters L., Hübner E., Haas T., Heinemann F.W., Burzlaff N.
Publisher: Elsevier
Book Volume: 694
Pages Range: 2319-2327
Journal Issue: 15
DOI: 10.1016/j.jorganchem.2009.03.037
The tripodal N,N,O ligands 3,3-bis(3,5-dimethylpyrazol-1-yl)propionic acid (Hbdmpzp) (1) and 3,3-bis(pyrazol-1-yl)propionic acid (Hbpzp) (2) form the "missing link" between the well-known bis(pyrazol-1-yl)acetic acids and related ligands with a longer "carboxylate arm". To illustrate the reactivity of this ligand, manganese and rhenium complexes bearing the ligand bdmpzp are reported. The complexes are compared to related compounds bearing other tripod ligands such as bis(3,5-dimethylpyrazol-1-yl)acetate (bdmpza) and 3,3-bis(1-methylimidazol-2-yl)propionate (bmip). Spectroscopic and structural data are used as a basis for comparison, as well as DFT calculations. Both ligands 1 and 2 and the complexes fac-[Mn(bdmpzp)(CO) ] (3) and fac-[Re(bdmpzp)(CO) ] (4) were characterised by X-ray crystallography. © 2009 Elsevier B.V. All rights reserved.
APA:
Peters, L., Hübner, E., Haas, T., Heinemann, F.W., & Burzlaff, N. (2009). 3,3-Bis(3,5-dimethylpyrazol-1-yl)propionic acid: A tripodal N,N,O ligand for manganese and rhenium complexes - Syntheses and structures. Journal of Organometallic Chemistry, 694(15), 2319-2327. https://dx.doi.org/10.1016/j.jorganchem.2009.03.037
MLA:
Peters, Liv, et al. "3,3-Bis(3,5-dimethylpyrazol-1-yl)propionic acid: A tripodal N,N,O ligand for manganese and rhenium complexes - Syntheses and structures." Journal of Organometallic Chemistry 694.15 (2009): 2319-2327.
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