Liquid-Liquid Phase Behavior of Solutions of 1-Octyl- and 1-Decy1-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide (C(8,10)mimNTf(2)) in n-Alkyl Alcohols

Vale VR, Rathke B, Will S, Schröer W (2010)


Publication Language: English

Publication Status: Published

Publication Type: Journal article

Publication year: 2010

Journal

Publisher: American Chemical Society

Book Volume: 55

Pages Range: 2030-2038

Journal Issue: 5

DOI: 10.1021/je900988a

Abstract

Systematic measurements of liquid-liquid phase diagrams of binary mixtures of the ionic liquids 1-octyl-3-methylimidazolium bis(trifluoromethylsullonyl)imide (C(8)mimNTf(2)) and 1-decy1-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (C(10)mimNTf(2)) with n-alkyl alcohols (1-octanol, 1-nonanol, 1-decanol, 1-undecanol, 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol, and 1-eicosanol) were performed. The phase diagrams were obtained at atmospheric pressure in the temperature range (283 to 423) K applying the cloud-point method on a set of samples. With the assumption of Ising criticality, analysis of the shapes of the phase diagrams yielded data on the critical points and the parameters characterizing the width and the asymmetry of the coexistence curves.

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How to cite

APA:

Vale, V.R., Rathke, B., Will, S., & Schröer, W. (2010). Liquid-Liquid Phase Behavior of Solutions of 1-Octyl- and 1-Decy1-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide (C(8,10)mimNTf(2)) in n-Alkyl Alcohols. Journal of Chemical and Engineering Data, 55(5), 2030-2038. https://dx.doi.org/10.1021/je900988a

MLA:

Vale, Vlad R., et al. "Liquid-Liquid Phase Behavior of Solutions of 1-Octyl- and 1-Decy1-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide (C(8,10)mimNTf(2)) in n-Alkyl Alcohols." Journal of Chemical and Engineering Data 55.5 (2010): 2030-2038.

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