Continuous homogeneous hydrogenation reaction in micellar solution.

Schwarze M, Milano-Brusco JS, Wille S, Mokrushina L, Smirnova I, Arlt W, Schomäcker R (2010)

Publication Type: Conference contribution, Conference Contribution

Subtype: other

Publication year: 2010

Publisher: American Chemical Society

Pages Range: IEC-84

Conference Proceedings Title: Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010

Abstract

Homogeneous hydrogenation reactions are usually carried out in org. solvents but Oehme [1] has shown that e.g. Hydrogenation reactions can be transferred to water if surfactants are used as solubilizer. At surfactant concns. higher than the crit. micelle concn. (cmc), the surfactant monomers form micelles (nanoreactors) in which the catalyst can be embedded and where the reaction takes place. After reaction the micelles and therefore the catalyst can be sepd. from the reaction mixt. by an ultrafiltration membrane. For the development of a continuous hydrogenation process, more information about the hydrogenation in micellar solns. and the filtration of micellar solns. is needed. In this contribution we discuss parameters that influence the process performance and show examples for the continuous rhodium catalyzed hydrogenation reaction in micellar soln. We thank German National Science Foundation (grant SCHO 687/7-1) for financial support. [on SciFinder(R)]

Authors with CRIS profile

Liudmila Mokrushina Lehrstuhl für Thermische Verfahrenstechnik Wolfgang Arlt Lehrstuhl für Thermische Verfahrenstechnik

Involved external institutions

Technische Universität Berlin DE Germany (DE) Technische Universität Hamburg-Harburg (TUHH) DE Germany (DE)

How to cite

APA:

Schwarze, M., Milano-Brusco, J.S., Wille, S., Mokrushina, L., Smirnova, I., Arlt, W., & Schomäcker, R. (2010). Continuous homogeneous hydrogenation reaction in micellar solution. In Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010 (pp. IEC-84). American Chemical Society.

MLA:

Schwarze, Michael, et al. "Continuous homogeneous hydrogenation reaction in micellar solution." Proceedings of the Abstracts of Papers, 239th ACS National Meeting, San Francisco, CA, United States, March 21-25, 2010 American Chemical Society, 2010. IEC-84.

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