Synthesis and luminescent properties of Eu3+/Eu2+ co-doped calcium aluminosilicate glass-ceramics

Bouchouicha H, Panczer G, de Ligny D, Guyot Y, Baesso ML, Andrade LHC, Lima SM, Ternane R (2016)


Publication Status: Published

Publication Type: Conference contribution

Publication year: 2016

Journal

Publisher: Elsevier

Book Volume: 169

Pages Range: 528-533

DOI: 10.1016/j.jlumin.2014.11.054

Abstract

Eu2+ and Eu2+ co-doped calcium aluminosilicate glass-ceramics have been prepared by devitrification of calcium aluminosilicate glass using heat-treatment. Control of crystallization in the glass-ceramics was studied by X-ray diffraction (XRD) and Raman spectroscopy. The results showed that crystalline phases in glass-ceramic belong to the family of melilite Ca2Mg0.25Al1.5Si1.25O7 as the major phase and anorthite CaAl2Si2O8 as the minor phase. Luminescent properties were investigated by emission; lifetime and the color points were calculated. Emission spectra showed that Eu2+ entered into the crystalline phase in a two steps mechanism: first as Eu2+ which is then reduced to Eu2+. This incorporation in the crystal enhanced Eu2+ emission with increasing time of heat-treatment and therefore crystallization. (C) 2014 Elsevier B.V. All rights reserved.

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APA:

Bouchouicha, H., Panczer, G., de Ligny, D., Guyot, Y., Baesso, M.L., Andrade, L.H.C.,... Ternane, R. (2016). Synthesis and luminescent properties of Eu3+/Eu2+ co-doped calcium aluminosilicate glass-ceramics. (pp. 528-533). Elsevier.

MLA:

Bouchouicha, H., et al. "Synthesis and luminescent properties of Eu3+/Eu2+ co-doped calcium aluminosilicate glass-ceramics." Elsevier, 2016. 528-533.

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