A cis-Divacant Octahedral and Mononuclear Iron(IV) Imide

Searles K, Fortier S, Khusniyarov M, Carroll PJ, Sutter J, Meyer K, Mindiola DJ, Caulton KG (2014)

Publication Status: Published

Publication Type: Journal article

Publication year: 2014

Journal

Angewandte Chemie International Edition Wiley

Publisher: Wiley-VCH Verlag

Book Volume: 53

Pages Range: 14139-14143

DOI: 10.1002/anie.201407156

Abstract

A rare, low-spin Fe-IV imide complex [(pyrr(2)py)-Fe=NAd] (pyrr(2)py(2-) = bis(pyrrolyl)pyridine; Ad = 1-adamantyl) confined to a cis-divacant octahedral geometry, was prepared by reduction of N(3)Ad by the FeII precursor [(pyrr(2)py)Fe(OEt2)]. The imide complex is low-spin with temperature-independent paramagnetism. In comparison to an authentic Fe-III complex, such as [(pyrr(2)py)FeCl], the pyrr(2)py(2-) ligand is virtually redox innocent.

Authors with CRIS profile

Marat Khusniyarov Lehrstuhl für Anorganische und Allgemeine Chemie Jörg Sutter Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

University of Pennsylvania US United States (USA) (US) The University of Texas at El Paso US United States (USA) (US) Indiana University US United States (USA) (US)

How to cite

APA:

Searles, K., Fortier, S., Khusniyarov, M., Carroll, P.J., Sutter, J., Meyer, K.,... Caulton, K.G. (2014). A cis-Divacant Octahedral and Mononuclear Iron(IV) Imide. Angewandte Chemie International Edition, 53, 14139-14143. https://dx.doi.org/10.1002/anie.201407156

MLA:

Searles, Keith, et al. "A cis-Divacant Octahedral and Mononuclear Iron(IV) Imide." Angewandte Chemie International Edition 53 (2014): 14139-14143.

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