New route to biaryl phosphanes with axial chirality as ligands for enantioselective hydrogenations.

Drießen-Hölscher B, Kralik J, Agel F, Steffens C, Hu C (2004)


Publication Language: English

Publication Type: Journal article, Original article

Subtype: other

Publication year: 2004

Journal

Publisher: Wiley-VCH Verlag

Book Volume: 346

Pages Range: 979-982

Journal Issue: 8

DOI: 10.1002/adsc.200404034

Abstract

The authors found a modular route for the synthesis of Cl-MeOBIPHEP ligands (I; R = Ph, p-FC6H4, xylyl, 2-furyl, 2,5-(MeO)2C6H3) via the corresponding biphenol that allows the authors to introduce several substituents without the necessity to sep. the enantiomers of each deriv. These new diphosphines were used to prepn. Ru(I)(O2CCF3)2 for use in the Ru-catalyzed enantioselective hydrogenation of di-Me itaconate with ee values up to 97%. [on SciFinder(R)]

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How to cite

APA:

Drießen-Hölscher, B., Kralik, J., Agel, F., Steffens, C., & Hu, C. (2004). New route to biaryl phosphanes with axial chirality as ligands for enantioselective hydrogenations. Advanced Synthesis & Catalysis, 346(8), 979-982. https://dx.doi.org/10.1002/adsc.200404034

MLA:

Drießen-Hölscher, Birgit, et al. "New route to biaryl phosphanes with axial chirality as ligands for enantioselective hydrogenations." Advanced Synthesis & Catalysis 346.8 (2004): 979-982.

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