Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions.

Other publication type
(Patent)


Publication Details

Author(s): Szesni N, Wasserscheid P, Fischer R, Haumann M, Werner S, Kaiser M
Publisher: Szesni, Normen, Germany .
Publication year: 2011
Journal issue: DE102009038690A1
Pages range: 36pp.; Chemical Indexing Equivalent to 154:287918 (DE)


Abstract


Water gas shift reaction catalysts for reaction under mild conditions use a solid support contg. an active catalyst, an ionic liq., and a co-activator, in which the active catalyst is a metal carbonyl of general formulas [M(CO)x(L)yClz], in which M = Cr, Mo, W, Ru, Fe, Co, Rh, Ir, Mn, Re, Ni, Pd, Pt, Cu, Ag, Au, or Zn; x = 0-6, y = 0-4, z = 1-6, and n = 1, 2, 3, 4, or >4; L is a monodentate or oligodentate donor ligand (e.g., amines, phosphanes, phosphite, arsanes, stibanes, or heterocyclic systems, such as pyridine, bipyridine, phenanthroline, or N-heterocyclic carbene ligands). The ionic liq. is of general structure [A]n+[Y],sup.n- (n = 1 or 2), in which Y is an org. or inorg. anion, and A is an onium cation, such as quaternary ammonium, quaternary phosphonium, sulfonium, guanidinium, imidazolium, pyridinium, pyrazolium, and 1,3,5-triazolium. [on SciFinder(R)]



FAU Authors / FAU Editors

Haumann, Marco PD Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik
Werner, Sebastian
Graduiertenzentrum der FAU


External institutions
Clariant Deutschland


How to cite

APA:
Szesni, N., Wasserscheid, P., Fischer, R., Haumann, M., Werner, S., & Kaiser, M. (2011). Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions. Szesni, Normen, Germany ..

MLA:
Szesni, Normen, et al. Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions. Szesni, Normen, Germany ., 2011.

BibTeX: 

Last updated on 2018-10-08 at 03:24