Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions.

Weiterer Publikationstyp
(Patent)


Details zur Publikation

Autor(en): Szesni N, Wasserscheid P, Fischer R, Haumann M, Werner S, Kaiser M
Verlag: Szesni, Normen, Germany .
Jahr der Veröffentlichung: 2011
Heftnummer: DE102009038690A1
Seitenbereich: 36pp.; Chemical Indexing Equivalent to 154:287918 (DE)


Abstract


Water gas shift reaction catalysts for reaction under mild conditions use a solid support contg. an active catalyst, an ionic liq., and a co-activator, in which the active catalyst is a metal carbonyl of general formulas [M(CO)x(L)yClz], in which M = Cr, Mo, W, Ru, Fe, Co, Rh, Ir, Mn, Re, Ni, Pd, Pt, Cu, Ag, Au, or Zn; x = 0-6, y = 0-4, z = 1-6, and n = 1, 2, 3, 4, or >4; L is a monodentate or oligodentate donor ligand (e.g., amines, phosphanes, phosphite, arsanes, stibanes, or heterocyclic systems, such as pyridine, bipyridine, phenanthroline, or N-heterocyclic carbene ligands). The ionic liq. is of general structure [A]n+[Y],sup.n- (n = 1 or 2), in which Y is an org. or inorg. anion, and A is an onium cation, such as quaternary ammonium, quaternary phosphonium, sulfonium, guanidinium, imidazolium, pyridinium, pyrazolium, and 1,3,5-triazolium. [on SciFinder(R)]



FAU-Autoren / FAU-Herausgeber

Haumann, Marco PD Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik
Werner, Sebastian
Graduiertenzentrum der FAU


Autor(en) der externen Einrichtung(en)
Clariant Deutschland


Zitierweisen

APA:
Szesni, N., Wasserscheid, P., Fischer, R., Haumann, M., Werner, S., & Kaiser, M. (2011). Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions. Szesni, Normen, Germany ..

MLA:
Szesni, Normen, et al. Transition metal carbonyl catalysts with ionic liquids for water gas shift reaction under mild conditions. Szesni, Normen, Germany ., 2011.

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Zuletzt aktualisiert 2018-10-08 um 03:24