Regiochemistry of azide additions to [7O]fullerene

Nuber B, Hirsch A (1996)


Publication Type: Journal article, Original article

Publication year: 1996

Journal

Original Authors: Nuber B., Hirsch A.

Book Volume: 4

Pages Range: 715-728

Journal Issue: 4

URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0030198236&origin=inward

Abstract

In this paper we report for the first time on the reaction of C with alkyl azides and show that the [3+2]-cycloaddition occurs preferably at bond 7 followed by bond 5 to give two regioisomeric A/B-triazolines and one C/C-triazoline. Thermal extrusion of N from these triazolines leads to open [5,6]-bridged iminofullerenes as A/A- and B/C-isomers as well as to the ring closed [6,6]-bridged analogues as A/B- and C/C-isomers. These results are in line with the corresponding thermal reaction of C with diazomethane.

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How to cite

APA:

Nuber, B., & Hirsch, A. (1996). Regiochemistry of azide additions to [7O]fullerene. Fullerene Science and Technology, 4(4), 715-728.

MLA:

Nuber, Berthold, and Andreas Hirsch. "Regiochemistry of azide additions to [7O]fullerene." Fullerene Science and Technology 4.4 (1996): 715-728.

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