Change in reaction kinetics of a Portland Cement caused by a superplasticizer – Calculation of heat flow curves from XRD data

Journal article


Publication Details

Author(s): Jansen D, Neubauer J, Götz-Neunhoeffer F, Härzschel R, Hergeth WD
Journal: Cement and Concrete Research
Publisher: Elsevier
Publication year: 2012
Journal issue: 42
Pages range: 327-332
ISSN: 0008-8846


Abstract


The hydration process of a commercial Portland cement was followed by means of heat flow calorimetry. The measured heat flow was compared with calculated heat flow curves based on XRD data. Examined in particular was the influence of one selected superplasticizer on the hydration of the Portland cement. It was shown that the superplasticizer in question retards both the aluminate reaction and the silicate reaction. It is certainly conceivable that there are more than only one explanation for the interaction between the superplasticizer and the cement. A complexation of Ca 2 + ions from pore solution by the superplasticizer is as thinkable as the adsorption of the polymer on the nuclei or the anhydrous grain surfaces which in turn might lead to the prevention of the growth of the nuclei or the dissolution of the anhydrous grains. © 2011 Elsevier Ltd. All rights reserved.



FAU Authors / FAU Editors

Götz-Neunhoeffer, Friedlinde Prof. Dr.
Lehrstuhl für Mineralogie
Jansen, Daniel Dr.
Lehrstuhl für Mineralogie
Neubauer, Jürgen apl. Prof. Dr.
Lehrstuhl für Mineralogie


External institutions
Wacker Chemie AG


How to cite

APA:
Jansen, D., Neubauer, J., Götz-Neunhoeffer, F., Härzschel, R., & Hergeth, W.D. (2012). Change in reaction kinetics of a Portland Cement caused by a superplasticizer – Calculation of heat flow curves from XRD data. Cement and Concrete Research, 42, 327-332. https://dx.doi.org/10.1016/j.cemconres.2011.10.005

MLA:
Jansen, Daniel, et al. "Change in reaction kinetics of a Portland Cement caused by a superplasticizer – Calculation of heat flow curves from XRD data." Cement and Concrete Research 42 (2012): 327-332.

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Last updated on 2018-09-08 at 16:08