Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate
Iskhakova GG, Kiselev VD, van Eldik R, Zahl A, Shihab MS, Konovalov AI (2011)
Publication Type: Journal article, Original article
Publication year: 2011
Journal
Original Authors: Iskhakova G., Kiselev V., Van Eldik R., Zahl A., Shihab M., Konovalov A.
Publisher: Wiley-Blackwell
Book Volume: 24
Pages Range: 360-365
Journal Issue: 5
DOI: 10.1002/poc.1765
Abstract
Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate at 298.2 K are reported. This equilibrium is shifted to the phosphobetaine in polar solvents, salt solutions and under high external pressure. The reaction volume changes dramatically on going from less polar diethyl ether (-69 cm mol) and tetrahydrofurane (THF) (-66 cm mol ), to more polar acetonitrile (-39 cm mol) and acetone (-38 cm mol). Copyright © 2010 John Wiley & Sons, Ltd.
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APA:
Iskhakova, G.G., Kiselev, V.D., van Eldik, R., Zahl, A., Shihab, M.S., & Konovalov, A.I. (2011). Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate. Journal of Physical Organic Chemistry, 24(5), 360-365. https://doi.org/10.1002/poc.1765
MLA:
Iskhakova, Gulnara G., et al. "Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tri-n-butylphosphoniumdithiocarboxylate." Journal of Physical Organic Chemistry 24.5 (2011): 360-365.
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