Effective chirality transfer in ionic liquids through ion-pairing effects.

Journal article
(Original article)


Publication Details

Author(s): Schulz P, Bösmann A, Wasserscheid P
Journal: Angewandte Chemie-International Edition
Publisher: Wiley-VCH Verlag
Publication year: 2007
Volume: 46
Journal issue: 8
Pages range: 1293-1295
ISSN: 1433-7851


Abstract


Since every reaction at a prochiral ion must take place in close proximity to its counterion, it should be possible to transfer chiral information between the ions of an ionic liq. Indeed, the hydrogenation of a prochiral, keto-functionalized cation was found to proceed in the presence of (R)-camphorsulfonate in up to 80% ee. [on SciFinder(R)]



FAU Authors / FAU Editors

Bösmann, Andreas Dr.
Schulz, Peter Dr.
Lehrstuhl für Chemische Reaktionstechnik
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik

Last updated on 2018-11-08 at 02:16