In situ structural analysis of calcium aluminosilicate glasses under high pressure

Beitrag in einer Fachzeitschrift

Details zur Publikation

Autor(en): Muniz RF, de Ligny D, Martinet C, Sandrini M, Medina AN, Rohling JH, Baesso ML, Lima SM, Andrade LHC, Guyot Y
Zeitschrift: Journal of Physics: Condensed Matter
Verlag: Institute of Physics: Hybrid Open Access
Jahr der Veröffentlichung: 2016
Band: 28
Heftnummer: 31
ISSN: 0953-8984
eISSN: 1361-648X


In situ micro-Raman spectroscopy was used to investigate the structural evolution of OH--free calcium aluminosilicate glasses, under high pressure and at room temperature. Evaluation was made of the role of the SiO2 concentration in percalcic join systems, for Al/(Al + Si) in the approximate range from 0.9 to 0.2. Under high pressure, the intensity of the main band related to the bending mode of bridging oxygen (nu(B)[T-O-T], where T = Si or Al) decreased gradually, suggesting that the bonds were severely altered or even destroyed. In Si-rich glasses, compression induced a transformation of Qn species to Qn-1. In the case of Al-rich glass, the Al in the smallest Qn units evolved from tetrahedral to higher-coordinated Al ([5] Al and [6] Al). Permanent structural changes were observed in samples recovered from the highest pressure of around 15 GPa and, particularly for Si-rich samples, the recovered structure showed an increase of three-membered rings in the Si/Al tetrahedral network.

FAU-Autoren / FAU-Herausgeber

de Ligny, Dominique Prof. Dr.
Professur für Werkstoffwissenschaften (Glas und Keramik)

Autor(en) der externen Einrichtung(en)
Universidade Estadual de Maringá (UEM) / Maringá State University
Universidade Estadual de Mato Grosso do Sul (UEMS) / State University of Mato Grosso do Sul
Université Claude Bernard Lyon 1 (UCB)


Muniz, R.F., de Ligny, D., Martinet, C., Sandrini, M., Medina, A.N., Rohling, J.H.,... Guyot, Y. (2016). In situ structural analysis of calcium aluminosilicate glasses under high pressure. Journal of Physics: Condensed Matter, 28(31).

Muniz, R. F., et al. "In situ structural analysis of calcium aluminosilicate glasses under high pressure." Journal of Physics: Condensed Matter 28.31 (2016).


Zuletzt aktualisiert 2018-11-08 um 00:27