Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts

Kindt S, Wicht K, Heinrich M (2015)


Publication Language: English

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2015

Journal

Publisher: American Chemical Society

Book Volume: 17

Pages Range: 6122-6125

Journal Issue: 24

DOI: 10.1021/acs.orglett.5b03143

Abstract

A new transition-metal-free version of the Meerwein arylation has been developed. The key feature of this carboamination-type reaction is the slow base-controlled generation of aryl radicals from aryldiazonium tetrafluoroborates, so that a sufficient quantity of diazonium ions remains to enable efficient trapping of the alkyl radical adduct resulting from aryl radical addition to the alkene. Under strongly basic conditions, diazoanhydrides are likely to take over the role of the nitrogen-centered radical scavengers.

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How to cite

APA:

Kindt, S., Wicht, K., & Heinrich, M. (2015). Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts. Organic Letters, 17(24), 6122-6125. https://dx.doi.org/10.1021/acs.orglett.5b03143

MLA:

Kindt, Stephanie, Karina Wicht, and Markus Heinrich. "Base-Induced Radical Carboamination of Nonactivated Alkenes with Aryldiazonium Salts." Organic Letters 17.24 (2015): 6122-6125.

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