Bauer T, Hager V, Williams M, Laurin M, Döpper T, Görling A, Szesni N, Wasserscheid P, Haumann M, Libuda J (2017)
Publication Language: English
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 2017
Publisher: Wiley Blackwell
Book Volume: 9
Pages Range: 109-113
Journal Issue: 1
The ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate [EMIM][EtOSO] was supported on Pd-AlO to yield a solid catalyst with ionic liquid layer (SCILL) material. During the hydrogenation of ethene, it was found that ethene was incorporated into the imidazolium moiety in a reaction catalyzed by the palladium surface. The formation of 1,2-diethyl-3-methylimidazolium ethylsulfate was confirmed ex situ by means of NMR spectroscopy. Moreover, the reaction itself could be monitored in situ by diffuse reflection infrared Fourier transformation (DRIFT) spectroscopy. A reaction mechanism involving surface carbene species was proposed on the basis of the analytical data.
APA:
Bauer, T., Hager, V., Williams, M., Laurin, M., Döpper, T., Görling, A.,... Libuda, J. (2017). Palladium-Mediated Ethylation of the Imidazolium Cation Monitored In Operando on a Solid Catalyst with Ionic Liquid Layer. ChemCatChem, 9(1), 109-113. https://doi.org/10.1002/cctc.201601222
MLA:
Bauer, Tanja, et al. "Palladium-Mediated Ethylation of the Imidazolium Cation Monitored In Operando on a Solid Catalyst with Ionic Liquid Layer." ChemCatChem 9.1 (2017): 109-113.
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