Toward well-defined metal-polymer interfaces: Temperature-controlled suppression of subsurface diffusion and reaction at the calcium/poly(3- Hexylthiophene) interface
Bebensee F, Schmid M, Steinrück HP, Campbell CT, Gottfried M (2010)
Publication Type: Journal article
Publication year: 2010
Journal
Original Authors: Bebensee F., Schmid M., Steinrück H.-P., Campbell C.T., Gottfried J.M.
Publisher: American Chemical Society
Book Volume: 132
Pages Range: 12163-12165
Journal Issue: 35
DOI: 10.1021/ja104029r
Abstract
The thickness of the reaction zone at the interface between calcium and regioregular poly(3-hexylthiophene), which is one of the best performing metal/polymer combinations in photovoltaic devices, depends critically on the temperature of the polymer during the initial phase of metal deposition. It is shown that deposition at 130 K reduces the thickness of the reaction zone, an effect that also persists after warming to room temperature. © 2010 American Chemical Society.
Authors with CRIS profile
Fabian Bebensee
Graduiertenzentrum der FAU
Martin Schmid
Lehrstuhl für Physikalische Chemie II
Hans-Peter Steinrück
Lehrstuhl für Physikalische Chemie II
Michael Gottfried
Naturwissenschaftliche Fakultät
Additional Organisation(s)
Involved external institutions
United States (USA) (US)How to cite
APA:
Bebensee, F., Schmid, M., Steinrück, H.-P., Campbell, C.T., & Gottfried, M. (2010). Toward well-defined metal-polymer interfaces: Temperature-controlled suppression of subsurface diffusion and reaction at the calcium/poly(3- Hexylthiophene) interface. Journal of the American Chemical Society, 132(35), 12163-12165. https://dx.doi.org/10.1021/ja104029r
MLA:
Bebensee, Fabian, et al. "Toward well-defined metal-polymer interfaces: Temperature-controlled suppression of subsurface diffusion and reaction at the calcium/poly(3- Hexylthiophene) interface." Journal of the American Chemical Society 132.35 (2010): 12163-12165.
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