Synthesis and electrochemistry of diels-alder adducts of [60]fulierene with a phthalocyanine and a hemiporphyrazine

Dürr K, Fiedler S, Linßen T, Hirsch A, Hanack M (1997)


Publication Type: Journal article, Original article

Publication year: 1997

Journal

Original Authors: Dürr K., Fiedler S., Linßen T., Hirsch A., Hanack M.

Book Volume: 130

Pages Range: 1375-1378

Journal Issue: 10

URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0004962850&origin=inward

Abstract

The synthesis of a new Diels-Alder adduct 7 of [60]fullerene and a phthalocyaninenickel compound containing a longer spacer than the originally reported Diels-Alder adduct 1 is described. The bisenophilic hemiporphyrazinenickel compound 11 reacts with [60]fullerene to form a Diels-Alder adduct 12 containing two fullerene units. Spectroelectrochemi-cal investigations of 7 and 12 reveal multiple reductions, which are attributed to the corresponding subunits of the molecules. In contrast to 1, the electron acceptor properties of the [60]fullerene unit in both molecules have no influence on the electronic properties of the phthalocyanine and herniporphyrazine, respectively. © WILEY-VCH Verlag GmbH.

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How to cite

APA:

Dürr, K., Fiedler, S., Linßen, T., Hirsch, A., & Hanack, M. (1997). Synthesis and electrochemistry of diels-alder adducts of [60]fulierene with a phthalocyanine and a hemiporphyrazine. Chemische Berichte, 130(10), 1375-1378.

MLA:

Dürr, Kai, et al. "Synthesis and electrochemistry of diels-alder adducts of [60]fulierene with a phthalocyanine and a hemiporphyrazine." Chemische Berichte 130.10 (1997): 1375-1378.

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