Hanack M, Hirsch A, Kamenzin S, Thies R, Vermehren P (1991)
Publication Type: Journal article, Original article
Publication year: 1991
Original Authors: Hanack M., Hirsch A., Kamenzin S., Thies R., Vermehren P.
Publisher: Elsevier
Book Volume: 42
Pages Range: 2633-2636
Journal Issue: 3
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0026155789&origin=inward
Phthalocyaninato- and tetrapyrazoporpyhrazinato metal complexes PcM and TPzPM (M = Fe, Ru) which are treated with bidentate bridging ligands L [e.g. 1,4-diisocyanobenzene (dib) 2,3,5,6-tetramethyldiisocyanobenzene (medib), 4-isocyano-3,5-dimethylpyridine (mepyNC), pyrazine (pyz)] lead to linear bridged systems [PcM(L)] and [TPzPM(L)]. By using the peripherically substituted macrocycles t-BuPcM, and t-BuTPzPM the corresponding coordination oligomers are soluble in CHCl, CHCl or toluene. The average chain length can be determined by H-NMR-spectroscopy. If the bringing ligand is substituted with long side chains, e.g. 2,5-didecylpyrazine (decpyz) soluble coordination oligomers, e.g. [PcRu(decpyz)] are also obtained. © 1991.
APA:
Hanack, M., Hirsch, A., Kamenzin, S., Thies, R., & Vermehren, P. (1991). Soluble bridged phthalocyaninato transition metal complexes. Synthetic Metals, 42(3), 2633-2636.
MLA:
Hanack, Michael, et al. "Soluble bridged phthalocyaninato transition metal complexes." Synthetic Metals 42.3 (1991): 2633-2636.
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