Spherical Sila- and Germa-Homoaromaticity

Chen Z, Hirsch A, Nagase S, Thiel W, Schleyer P (2003)

Publication Type: Journal article, Original article

Publication year: 2003

Journal

Journal of the American Chemical Society American Chemical Society

Original Authors: Chen Z., Hirsch A., Nagase S., Thiel W., Von Rague Schleyer P.

Publisher: American Chemical Society

Book Volume: 125

Pages Range: 15507-15511

Journal Issue: 50

DOI: 10.1021/ja038005u

Abstract

Guided by the 2(N + 1) electron-counting rule for spherical aromatic molecules, we have designed various spherical sila- and germa-homoaromatic systems rich in group 14 elements. Their aromaticity is revealed by density-functional computations of their structures and the nucleus-independent chemical shifts (NICS). Besides the formerly used endohedral inclusion strategy, spherical homoaromaticity is another way to stabilize silicon and germanium clusters.

Authors with CRIS profile

Andreas Hirsch Lehrstuhl für Organische Chemie II Paul Schleyer Naturwissenschaftliche Fakultät

Involved external institutions

Kyoto University / 京都大学 Kyōto daigaku JP Japan (JP) Max-Planck-Institut für Kohlenforschung (MPI KoFo) / Max Planck Institute for Coal Research DE Germany (DE)

How to cite

APA:

Chen, Z., Hirsch, A., Nagase, S., Thiel, W., & Schleyer, P. (2003). Spherical Sila- and Germa-Homoaromaticity. Journal of the American Chemical Society, 125(50), 15507-15511. https://doi.org/10.1021/ja038005u

MLA:

Chen, Zhongfang, et al. "Spherical Sila- and Germa-Homoaromaticity." Journal of the American Chemical Society 125.50 (2003): 15507-15511.

BibTeX: Download