Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60
Elemes Y, Hirsch A, Ioannou J (2007)
Publication Type: Journal article, Original article
Publication year: 2007
Journal
Original Authors: Ioannou E., Hirsch A., Elemes Y.
Publisher: Elsevier
Book Volume: 63
Pages Range: 7070-7076
Journal Issue: 30
DOI: 10.1016/j.tet.2007.05.011
Abstract
C reacts thermally with 1,3-dipoles, formed in situ, from sulfide-bearing imines of glycine esters, and affords dihydro-pyrrolo [60]fullerene derivatives containing a vinylic sulfide group, which were isolated in good yields, and characterized with H and C NMR, FTIR, UV-vis spectroscopies, and with FAB, ESI mass spectrometries. The new derivatives contain a sulfide, an imine, and an ester functionality for further chemical transformations. Mechanistic considerations with regard to the loss of a mercaptan molecule in the course of the cycloaddition are deployed. © 2007 Elsevier Ltd. All rights reserved.
Authors with CRIS profile
Involved external institutions
University of Ioannina / Πανεπιστήμιο Ιωαννίνων
Greece (GR)
Imperial College London / The Imperial College of Science, Technology and Medicine
United Kingdom (GB)
Greece (GR)
Imperial College London / The Imperial College of Science, Technology and Medicine
United Kingdom (GB)
How to cite
APA:
Elemes, Y., Hirsch, A., & Ioannou, J. (2007). Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60. Tetrahedron, 63(30), 7070-7076. https://dx.doi.org/10.1016/j.tet.2007.05.011
MLA:
Elemes, Yiannis, Andreas Hirsch, and John Ioannou. "Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C60." Tetrahedron 63.30 (2007): 7070-7076.
BibTeX: Download