Synthesis of amphiphilic [60]fullerene [3:3]hexakisadducts with four spherically defined addend zones

Beuerle F, Hirsch A (2009)


Publication Type: Journal article, Original article

Publication year: 2009

Journal

Original Authors: Beuerle F., Hirsch A.

Publisher: Wiley-VCH Verlag

Book Volume: 15

Pages Range: 7447-7455

Journal Issue: 30

DOI: 10.1002/chem.200900330

Abstract

New [3:3]hexakisadducts 3, 6, and 7 have been synthesized by a stepwise addition of two tripodal malonate tethers to pristine [60]fullerene. For the first time, [3:3]hexakisadducts of two sets of asymmetrically substituted malonate addends could be prepared as single in/out isomers by following this synthetic protocol. Thereby, four spherically defined addend zones I-IV were created with various similar degrees of latitude on the fullerene sphere. Four amphiphilic [3:3]hexakisadducts 12, 14, 18, and 19 were prepared with different relative arrangements of both the hydrophilic and lipophilic moieties in the addend zones I/II and III/IV, respectively. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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APA:

Beuerle, F., & Hirsch, A. (2009). Synthesis of amphiphilic [60]fullerene [3:3]hexakisadducts with four spherically defined addend zones. Chemistry - A European Journal, 15(30), 7447-7455. https://dx.doi.org/10.1002/chem.200900330

MLA:

Beuerle, Florian, and Andreas Hirsch. "Synthesis of amphiphilic [60]fullerene [3:3]hexakisadducts with four spherically defined addend zones." Chemistry - A European Journal 15.30 (2009): 7447-7455.

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