Modified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units ? Implications from spectroscopy
Meyer-Ilse J, Bauroth S, Braeutigam M, Schmitt M, Popp J, Beckert R, Rockstroh N, Pilz TD, Monczak K, Heinemann FW, Rau S, Dietzek B (2014)
Publication Status: Published
Publication Type: Journal article
Publication year: 2014
Journal
Publisher: ROYAL SOC CHEMISTRY
Book Volume: 43
Pages Range: 17659-17665
Journal Issue: 47
DOI: 10.1039/c4dt01399a
Abstract
The photophysical properties of Ruthenium-bipyridine complexes bearing a bibenzimidazole ligand were investigated. The nitrogens on the bibenzimidazole-ligand were protected, by adding either a phenylene group or a 1,2-ethandiyl group, to remove the photophysical dependence of the complex on the protonation state of the bibenzimidazole ligand. This protection results in the bibenzimidazole ligand contributing to the MLCT transition, which is experimentally evidenced by (resonance) Raman scattering in concert with DFT calculations for a detailed mode assignment in the (resonance) Raman spectra.
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Germany (DE)How to cite
APA:
Meyer-Ilse, J., Bauroth, S., Braeutigam, M., Schmitt, M., Popp, J., Beckert, R.,... Dietzek, B. (2014). Modified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units ? Implications from spectroscopy. Dalton Transactions, 43(47), 17659-17665. https://dx.doi.org/10.1039/c4dt01399a
MLA:
Meyer-Ilse, Julia, et al. "Modified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units ? Implications from spectroscopy." Dalton Transactions 43.47 (2014): 17659-17665.
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