Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions

Journal article
(Original article)


Publication Details

Author(s): Rohr U, Schatz J, Sauer J
Journal: European Journal of Organic Chemistry
Publisher: Wiley-VCH Verlag
Publication year: 1998
Journal issue: 12
Pages range: 2875-2883
ISSN: 1434-193X


Abstract


Normal, neutral, and inverse-type Diels-Alder reactions can be observed in [4+2] cycloadditions of thio- and selenocarbonyl compounds 1-9 with various cyclic and aryl-, methyl- or methoxy-substituted open-chain 1,3-butadienes. Extensive kinetic studies prove the highly dienophilic activity of the C=S and C=Se double bond. Studies of the solvent and temperature dependence of the reaction rate indicate a concerted mechanism.



FAU Authors / FAU Editors

Schatz, Jürgen Prof. Dr.
Professur für Organische Chemie


How to cite

APA:
Rohr, U., Schatz, J., & Sauer, J. (1998). Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions. European Journal of Organic Chemistry, 12, 2875-2883.

MLA:
Rohr, Uwe, Jürgen Schatz, and Jürgen Sauer. "Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions." European Journal of Organic Chemistry 12 (1998): 2875-2883.

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Last updated on 2019-22-04 at 14:50