Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions

Rohr U, Schatz J, Sauer J (1998)


Publication Type: Journal article, Original article

Publication year: 1998

Journal

Original Authors: Rohr U., Schatz J., Sauer J.

Publisher: Wiley-VCH Verlag

Pages Range: 2875-2883

Journal Issue: 12

URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0003128026&origin=inward

Abstract

Normal, neutral, and inverse-type Diels-Alder reactions can be observed in [4+2] cycloadditions of thio- and selenocarbonyl compounds 1-9 with various cyclic and aryl-, methyl- or methoxy-substituted open-chain 1,3-butadienes. Extensive kinetic studies prove the highly dienophilic activity of the C=S and C=Se double bond. Studies of the solvent and temperature dependence of the reaction rate indicate a concerted mechanism.

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How to cite

APA:

Rohr, U., Schatz, J., & Sauer, J. (1998). Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions. European Journal of Organic Chemistry, 12, 2875-2883.

MLA:

Rohr, Uwe, Jürgen Schatz, and Jürgen Sauer. "Thio- and Selenocarbonyl Compounds as "Superdienophiles" in [4+2] Cycloadditions." European Journal of Organic Chemistry 12 (1998): 2875-2883.

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