Continuous Gas-Phase Hydroformylation of a Highly Diluted Technical C4 Feed using Supported Ionic Liquid Phase Catalysts

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Haumann M, Jakuttis M, Franke R, Schönweiz A, Wasserscheid P
Zeitschrift: ChemCatChem
Verlag: Wiley-VCH Verlag
Jahr der Veröffentlichung: 2011
Band: 3
Heftnummer: 11
Seitenbereich: 1822--1827
ISSN: 1867-3880


Abstract


The concept of supported ionic liquid phase (SILP) catalysis has been established in recent years by our group and others. Its application in continuous catalytic gas-phase processes provides a very attractive way to bridge the gap between homogeneous and heterogeneous catalysis. In this contribution, we extend SILP hydroformylation catalysis to reactions with a highly diluted, technical C4 feed containing 1.5 {\%} 1-butene, 28.5 {\%} 2-butenes, and 70 {\%} of inert n-butane. To obtain the desired product, n-pentanal, the Rh-biphephos catalyst system was immobilized in the SILP system to allow for consecutive isomerization/hydroformylation activity. The resulting SILP catalyst material converted up to 81 {\%} of the reactive butenes, with a residence time of 155s in the reactor. An n-pentanal selectivity greater than 92{\%} was realized for more than 500h time-on-stream in the continuous gas-phase reaction. Post-reaction NMR studies revealed no significant loss of the phosphite ligand through ligand oxidation during the reaction.



FAU-Autoren / FAU-Herausgeber

Haumann, Marco PD Dr.
Lehrstuhl für Chemische Reaktionstechnik
Jakuttis, Michael
Lehrstuhl für Chemische Reaktionstechnik
Schönweiz, Andreas
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Autor(en) der externen Einrichtung(en)
Evonik Degussa GmbH


Zitierweisen

APA:
Haumann, M., Jakuttis, M., Franke, R., Schönweiz, A., & Wasserscheid, P. (2011). Continuous Gas-Phase Hydroformylation of a Highly Diluted Technical C4 Feed using Supported Ionic Liquid Phase Catalysts. ChemCatChem, 3(11), 1822--1827. https://dx.doi.org/10.1002/cctc.201100117

MLA:
Haumann, Marco, et al. "Continuous Gas-Phase Hydroformylation of a Highly Diluted Technical C4 Feed using Supported Ionic Liquid Phase Catalysts." ChemCatChem 3.11 (2011): 1822--1827.

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Zuletzt aktualisiert 2018-06-08 um 15:24