Catalyst recycling in monophasic Pt-catalyzed hydrosilylation reactions using ionic liquids
Taccardi N, Fekete M, Berger M, Stanjek V, Schulz P, Wasserscheid P (2011)
Publication Type: Journal article
Publication year: 2011
Journal
Publisher: Elsevier
Book Volume: 399
Pages Range: 69--74
Volume: 399
Issue: 1-2
Journal Issue: 1-2
DOI: 10.1016/j.apcata.2011.03.041
Abstract
The technical relevant Pt-catalyzed hydrosilylation of allyl chloride with trichlorosilane was investigated in a monophasic reaction system containing an ionic liquid (IL) additive. ILs screening allowed us to identify the liquid 1-decyl-3-methylimidazolium bis(trifloromethanesulfonyl)amide ([DMIM][NTf2]) as the best additive for such process. This IL combined complete miscibility with reactants as long as chemical and thermal robustness. After the reaction, the hydrosilylation product (3-chloropropyl)trichlorosilane was distilled off and the residual IL/catalyst solution could be reused. In such a way, a final TON of 14,200 was achieved over 10 reaction/distillation cycles without any loss of catalytic activity. The ability of [DMIM][NTf2] to prevent catalyst decomposition was deeper investigated and it was found that even with a Pt loading as high as 9500~ppm, the IL acted as protective/stabilizing agent for the catalyst during the thermally stressing product distillation.
Authors with CRIS profile
Nicola Taccardi
Lehrstuhl für Chemische Reaktionstechnik
Markus Berger
Lehrstuhl für Chemische Reaktionstechnik
Peter Schulz
Lehrstuhl für Chemische Reaktionstechnik
Peter Wasserscheid
Lehrstuhl für Chemische Reaktionstechnik
Additional Organisation(s)
Involved external institutions
Germany (DE)How to cite
APA:
Taccardi, N., Fekete, M., Berger, M., Stanjek, V., Schulz, P., & Wasserscheid, P. (2011). Catalyst recycling in monophasic Pt-catalyzed hydrosilylation reactions using ionic liquids. Applied Catalysis A-General, 399(1-2), 69--74. https://dx.doi.org/10.1016/j.apcata.2011.03.041
MLA:
Taccardi, Nicola, et al. "Catalyst recycling in monophasic Pt-catalyzed hydrosilylation reactions using ionic liquids." Applied Catalysis A-General 399.1-2 (2011): 69--74.
BibTeX: Download