Liquid silver tris(perfluoroethyl)trifluorophosphate salts as new media for propene/propane separation

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Pliquett D, Schulz P, Heinemann F, Bause A, Wasserscheid P
Zeitschrift: Physical Chemistry Chemical Physics
Verlag: Royal Society of Chemistry
Jahr der Veröffentlichung: 2016
Band: 18
Heftnummer: 40
Seitenbereich: 28242-28253
ISSN: 1463-9076
eISSN: 1463-9084


Abstract


A series of silver tris(perfluoroethyl) trifluorophosphate (Ag[FAP]) complexes with various ligands (acetonitrile ACN, chloroacetonitrile Cl-ACN, acrylonitrile acryl-CN, pyridine py, ethylenediamine en and propene C3H6) have been synthesized starting from Ag[NO3] and K[FAP] using three different routes. Physicochemical properties as well as crystal structures ([Ag(ACN)(2/4)][FAP], [Ag(py) 2][FAP]) were determined and the suitability of such Ag salts for propene/propane separation processes was investigated. The investigated silver complexes exhibit either low melting points or form liquid complexes when contacted with gaseous propene at 30 degrees C. This makes them promising separation materials for both liquid membranes and absorber fluids due to their high silver content and significant propene capacity. Single (iGSC) and mixed (NMR) gas solubilities as well as diffusion coefficients (PFG-NMR) of propene and propane were determined to predict the theoretical selectivity of solubility, membrane selectivity, capacity and transport properties of the silver salts according to the solution diffusion model. A strong influence of the number and type of ligands on chemical complexation, physicochemical properties and separation performance has been observed.



FAU-Autoren / FAU-Herausgeber

Heinemann, Frank Dr.
Lehrstuhl für Anorganische und Allgemeine Chemie
Pliquett, Daniel
Lehrstuhl für Chemische Reaktionstechnik
Schulz, Peter Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Autor(en) der externen Einrichtung(en)
Merck KGaA


Zitierweisen

APA:
Pliquett, D., Schulz, P., Heinemann, F., Bause, A., & Wasserscheid, P. (2016). Liquid silver tris(perfluoroethyl)trifluorophosphate salts as new media for propene/propane separation. Physical Chemistry Chemical Physics, 18(40), 28242-28253. https://dx.doi.org/10.1039/c6cp05653a

MLA:
Pliquett, Daniel, et al. "Liquid silver tris(perfluoroethyl)trifluorophosphate salts as new media for propene/propane separation." Physical Chemistry Chemical Physics 18.40 (2016): 28242-28253.

BibTeX: 

Zuletzt aktualisiert 2018-11-08 um 02:16