Electron-rich, Nitrido-bridged Ruthenium Complexes

Glueer A, Askevold B, Schluschass B, Heinemann FW, Schneider S (2015)

Publication Status: Published

Publication Type: Journal article

Publication year: 2015

Journal

Zeitschrift für Anorganische und Allgemeine Chemie Wiley

Publisher: Wiley-VCH Verlag

Book Volume: 641

Pages Range: 49-51

DOI: 10.1002/zaac.201400166

Abstract

Terminal Ru-IV nitride [RuN{N(CH2CH2PtBu2)(2)}] (1) and [RuCl{N(CH2CH2PtBu2)(2)}] (2a) form an equilibrium with bridging nitride [{(tBu(2)PCH(2)CH(2))(2)N} Ru(mu-N) RuCl{N(CH2CH2PtBu2)(2)}] (3a). While 3a could only be spectroscopically characterized yet not isolated, the reaction of the divinylamido chloro complex [RuCl{N(CHCHPtBu2)(2)}] (2b) with half an equivalent azide directly gave the analogous bridging nitride [{(tBu(2)PCHCH)(2)N} Ru(mu N) RuCl{N(CHCHPtBu2)(2)}] (3b), which was isolated and fully characterized.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Georg-August-Universität Göttingen DE Germany (DE)

How to cite

APA:

Glueer, A., Askevold, B., Schluschass, B., Heinemann, F.W., & Schneider, S. (2015). Electron-rich, Nitrido-bridged Ruthenium Complexes. Zeitschrift für Anorganische und Allgemeine Chemie, 641, 49-51. https://dx.doi.org/10.1002/zaac.201400166

MLA:

Glueer, Arne, et al. "Electron-rich, Nitrido-bridged Ruthenium Complexes." Zeitschrift für Anorganische und Allgemeine Chemie 641 (2015): 49-51.

BibTeX: Download