Nanoscale Morphology of PTB7 Based Organic Photovoltaics as a Function of Fullerene Size

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autorinnen und Autoren: Roehling JD, Baran D, Sit J, Kassar T, Ameri T, Unruh T, Brabec C, Moule AJ
Zeitschrift: Scientific Reports
Verlag: Nature Publishing Group: Open Access Journals - Option B
Jahr der Veröffentlichung: 2016
Band: 6
ISSN: 2045-2322
Sprache: Englisch


Abstract


High efficiency polymer:fullerene photovoltaic device layers self-assemble with hierarchical features from ångströms to 100's of nanometers. The feature size, shape, composition, orientation, and order all contribute to device efficiency and are simultaneously difficult to study due to poor contrast between carbon based materials. This study seeks to increase device efficiency and simplify morphology measurements by replacing the typical fullerene acceptor with endohedral fullerene LuN@PC BEH. The metal atoms give excellent scattering contrast for electron beam and X-ray experiments. Additionally, LuN@PC BEH has a lower electron affinity than standard fullerenes, which can raise the open circuit voltage of photovoltaic devices. Electron microscopy techniques are used to produce a detailed account of morphology evolution in mixtures of Lu 3 N@PC 80 BEH with the record breaking donor polymer, PTB7 and coated using solvent mixtures. We demonstrate that common solvent additives like 1,8-diiodooctane or chloronapthalene do not improve the morphology of endohedral fullerene devices as expected. The poor device performance is attributed to the lack of mutual miscibility between this particular polymer:fullerene combination and to co-crystallization of Lu 3 N@PC 80 BEH with 1,8-diiodooctane. This negative result explains why solvent additives mixtures are not necessarily a morphology cure-all.



FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Ameri, Tayebeh Dr.
Lehrstuhl für Werkstoffwissenschaften (Materialien der Elektronik und der Energietechnologie)
Baran, Derya
Lehrstuhl für Werkstoffwissenschaften (Materialien der Elektronik und der Energietechnologie)
Brabec, Christoph Prof. Dr.
Lehrstuhl für Werkstoffwissenschaften (Materialien der Elektronik und der Energietechnologie)
Kassar, Thaer
Professur für Nanomaterialcharakterisierung (Streumethoden)
Unruh, Tobias Prof. Dr.
Professur für Nanomaterialcharakterisierung (Streumethoden)


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Einrichtungen weiterer Autorinnen und Autoren

Lawrence Livermore National Laboratory
University of California Davis (UCDAVIS)


Forschungsbereiche

B Nanoelectronic Materials
Exzellenz-Cluster Engineering of Advanced Materials
A2 Nanoanalysis and Microscopy
Exzellenz-Cluster Engineering of Advanced Materials


Zitierweisen

APA:
Roehling, J.D., Baran, D., Sit, J., Kassar, T., Ameri, T., Unruh, T.,... Moule, A.J. (2016). Nanoscale Morphology of PTB7 Based Organic Photovoltaics as a Function of Fullerene Size. Scientific Reports, 6. https://dx.doi.org/10.1038/srep30915

MLA:
Roehling, John D., et al. "Nanoscale Morphology of PTB7 Based Organic Photovoltaics as a Function of Fullerene Size." Scientific Reports 6 (2016).

BibTeX: 

Zuletzt aktualisiert 2019-28-02 um 06:04