Giant Spherical Cluster with I-C-140 Fullerene Topology

Heinl S, Peresypkina E, Sutter J, Scheer M (2015)

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2015

Journal

Angewandte Chemie International Edition Wiley

Publisher: Wiley-VCH Verlag

Book Volume: 54

Pages Range: 13431-13435

DOI: 10.1002/anie.201505516

Abstract

We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp-R ligand in the pentatopic molecules [(CpFe)-Fe-R((5)-P-5)]. Using [(CpFe)-Fe-BIG((5)-P-5)] (Cp-BIG=C-5(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{(CpFe)-Fe-BIG((5:2:1:1:1:1:1)-P-5)}(12)(CuBr)(92)] is obtained. It shows topological analogy to the theoretically predicted I-C-140 fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state.

Authors with CRIS profile

Jörg Sutter Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Universität Regensburg DE Germany (DE)

How to cite

APA:

Heinl, S., Peresypkina, E., Sutter, J., & Scheer, M. (2015). Giant Spherical Cluster with I-C-140 Fullerene Topology. Angewandte Chemie International Edition, 54, 13431-13435. https://doi.org/10.1002/anie.201505516

MLA:

Heinl, Sebastian, et al. "Giant Spherical Cluster with I-C-140 Fullerene Topology." Angewandte Chemie International Edition 54 (2015): 13431-13435.

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