Ellermann J, Sutter J, Knoch F, Moll M, Bauer W (1994)
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 1994
Original Authors: Ellermann J, Sutter J, Knoch FA, Moll M, Bauer W
Publisher: Verlag der Zeitschrift Fuer Naturforschung
Book Volume: 49
Pages Range: 1763-1773
Journal Issue: 12
Reaction of Co(L-P,P)(L-N,P) (1; HL = Ph2PN:P(Ph2)N:(Ph2)PH) in CH2Cl2 with benzimidazole yields I.Cl. I.BPh4 was prepd. in THF by metathesis of I.Cl with NaBPh2. Deprotonation of the cationic ring in I.BPh4 was accomplished using 1,8-diazabicyclo[5.4.01,7]undec-7-ene and resulted in II. Treating 1 with 8-hydroxyquinoline (HQ) in CH2Cl2 yields the octahedral cis-CoQ2(L-P,P) (7). I.BPh4, II and 7 were characterized by their IR, Raman, 31P[1H] NMR, 13C[1H] NMR, 1H NMR and mass spectra. Crystals suitable for x-ray structure analyses were obtained for I.BPh4 and 7.0.5CH2Cl2. The colorless plates of I.BPh4 crystallize in the triclinic space group P̅1, with a 1172.7(3), b 1326.2(3), c 1806.1(6) pm; α 100.79(2), β 103.71(3), γ 108.18(2)°. The black blocks of 7.0.5CH2Cl2 crystallize in the monoclinic space group P21/c with a 1159.0(10), b 2008.9(10), c 2034.6(12) pm; β 105.86(5)°. [on SciFinder(R)]
APA:
Ellermann, J., Sutter, J., Knoch, F., Moll, M., & Bauer, W. (1994). Chemistry of polyfunctional molecules. 114. Synthesis and structure of an ionic and nonionic cyclic carbaphosphazene and of a cobalt(III) phosphazene complex. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 49(12), 1763-1773.
MLA:
Ellermann, J., et al. "Chemistry of polyfunctional molecules. 114. Synthesis and structure of an ionic and nonionic cyclic carbaphosphazene and of a cobalt(III) phosphazene complex." Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 49.12 (1994): 1763-1773.
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