Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Xu T, Wähler T, Vecchietti J, Bonivardi A, Bauer T, Schwegler J, Schulz P, Wasserscheid P, Libuda J
Zeitschrift: Angewandte Chemie-International Edition
Verlag: WILEY-V C H VERLAG GMBH
Jahr der Veröffentlichung: 2017
Band: 56
Heftnummer: 31
Seitenbereich: 9072-9076
ISSN: 1433-7851


Abstract


Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. Therefore, methods to control the chemistry and structure of this interface are the key to assemble new IL-based electronic and electrochemical materials. Here, we present a new method to prepare a chemically well-defined interface between an oxide and an IL film. An imidazolium-based IL, which is carrying an ester group, is deposited onto cobalt oxide surface by evaporation. The IL binds covalently to the surface by thermally activated cleavage of the ester group and formation of a bridging carboxylate. The anchoring reaction shows high structure sensitivity, which implies that the IL film can be adhered selectively to specific oxide surfaces.



FAU-Autoren / FAU-Herausgeber

Bauer, Tanja
Lehrstuhl für Physikalische Chemie II
Libuda, Jörg Prof. Dr.
Professur für Physikalische Chemie
Schulz, Peter Dr.
Lehrstuhl für Chemische Reaktionstechnik
Schwegler, Johannes
Lehrstuhl für Chemische Reaktionstechnik
Wähler, Tobias
Lehrstuhl für Physikalische Chemie II
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik
Xu, Tao
Lehrstuhl für Physikalische Chemie II


Autor(en) der externen Einrichtung(en)
INTEC - Instituto de Desarrollo Tecnológico para la Industria Química


Zitierweisen

APA:
Xu, T., Wähler, T., Vecchietti, J., Bonivardi, A., Bauer, T., Schwegler, J.,... Libuda, J. (2017). Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide. Angewandte Chemie-International Edition, 56(31), 9072-9076. https://dx.doi.org/10.1002/anie.201704107

MLA:
Xu, Tao, et al. "Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide." Angewandte Chemie-International Edition 56.31 (2017): 9072-9076.

BibTeX: 

Zuletzt aktualisiert 2018-06-08 um 12:23