Harnessing high-energy MLCT excited states for artificial photosynthesis
Cotic A, Ramírez-Wierzbicki I, Cadranel A (2024)
Publication Type: Journal article, Review article
Publication year: 2024
Journal
Book Volume: 514
Article Number: 215878
DOI: 10.1016/j.ccr.2024.215878
Abstract
Important fractions of the energy absorbed in natural and artificial photosynthetic schemes are dissipated via fast internal conversion processes. In contrast, chromophores that undergo internal conversion on slow timescales allow high-energy excited states to engage in bimolecular or long-range reactivity, outcompeting dissipation. This provides opportunities to improve solar energy conversion efficiencies. This review focuses on MLCT chromophores and analyzes fast and slow internal conversion processes in the form of inter-ligand electron transfer and hole reconfiguration. It discusses the current scenario, the obstacles, and the progress required to establish anti-dissipative molecular energy conversion schemes.
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Argentina (AR)How to cite
APA:
Cotic, A., Ramírez-Wierzbicki, I., & Cadranel, A. (2024). Harnessing high-energy MLCT excited states for artificial photosynthesis. Coordination Chemistry Reviews, 514. https://doi.org/10.1016/j.ccr.2024.215878
MLA:
Cotic, Agustina, Ivana Ramírez-Wierzbicki, and Alejandro Cadranel. "Harnessing high-energy MLCT excited states for artificial photosynthesis." Coordination Chemistry Reviews 514 (2024).
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