Monitoring structure and coordination chemistry of Co4O4-based oxygen evolution catalysts by nitrogen-14/-15 and cobalt-59 NMR spectroscopy
Uhlig F, Stammler MB, Meurer F, Shenderovich IG, Blahut J, Wisser FM (2024)
Publication Type: Journal article
Publication year: 2024
Journal
DOI: 10.1039/d4dt01273a
Abstract
The structural features of cobalt-based oxygen evolution catalysts are elucidated by combining high-field MAS NMR spectroscopy and DFT calculations. The superior photocatalytic activity of the heterogeneous system over its homogeneous counterpart is rationalised by the structural features. The higher activity is caused by a more favourable electron-withdrawing character of the framework.
Authors with CRIS profile
Involved external institutions
Universität Regensburg
Germany (DE)
Institute of Organic Chemistry and Biochemistry of the CAS
Czech Republic (CZ)
Germany (DE)
Institute of Organic Chemistry and Biochemistry of the CAS
Czech Republic (CZ)
How to cite
APA:
Uhlig, F., Stammler, M.B., Meurer, F., Shenderovich, I.G., Blahut, J., & Wisser, F.M. (2024). Monitoring structure and coordination chemistry of Co4O4-based oxygen evolution catalysts by nitrogen-14/-15 and cobalt-59 NMR spectroscopy. Dalton Transactions. https://doi.org/10.1039/d4dt01273a
MLA:
Uhlig, Felix, et al. "Monitoring structure and coordination chemistry of Co4O4-based oxygen evolution catalysts by nitrogen-14/-15 and cobalt-59 NMR spectroscopy." Dalton Transactions (2024).
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