High temperature oxidation and thermal properties of laminated Ti3Al(Si)C2-TiC/Nb based composites obtained by spark plasma sintering
Kashkarov EB, Abdulmenova AV, Pushilina NS, Syrtanov MS, Mingazova YR, Nassyrbayev A, Krotkevich DG, Travitzky N (2024)
Publication Type: Journal article
Publication year: 2024
Journal
Book Volume: 982
Article Number: 173848
DOI: 10.1016/j.jallcom.2024.173848
Abstract
This paper describes high-temperature oxidation behavior and thermal properties of metal-ceramic laminated composites fabricated by spark plasma sintering of Ti3Al(Si)C2-filled preceramic papers (TAC) and Nb foils. The high-temperature oxidation tests were carried out in air at 800–1300 °C. The phase composition and microstructure of the oxide layers were analyzed by X-ray diffraction and scanning electron microscopy, respectively. The thermal properties were measured by the laser flash method in the temperature range of 30–800 °C. The evolution of the microstructure of the reaction layer (RL) formed at TAC/Nb interfaces was studied. The passive oxidation of the surface TAC layers results in the formation of outer TiO2 and inner continuous Al2O3 phase at temperatures up to 1100 °C, while local accelerated oxidation occurs above 1100 °C. As a result of breakaway oxidation, a multilayer oxide structure consisting of TiO2, Al2TiO5, Al2O3 and SiO2 phases were formed. The oxidation of inner Nb layers from the side surface can lead to high volume expansion and generation of stresses in the ceramic and metal layers due to the formation of Nb2O5 oxide phase. The stress relaxation occurred by complex mechanisms, including plastic deformation of the Nb layers, delamination at the interfaces, and formation of cracks in the reaction and TAC layers. The high temperature exposure results in slight increase in columnar grains in the reaction layers at 1200 °C, while the thickness of RL remains unchanged. The TAC/Nb composites exhibit higher thermal conductivity and diffusivity compared to monolithic TAC ceramic composites.
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APA:
Kashkarov, E.B., Abdulmenova, A.V., Pushilina, N.S., Syrtanov, M.S., Mingazova, Y.R., Nassyrbayev, A.,... Travitzky, N. (2024). High temperature oxidation and thermal properties of laminated Ti3Al(Si)C2-TiC/Nb based composites obtained by spark plasma sintering. Journal of Alloys and Compounds, 982. https://doi.org/10.1016/j.jallcom.2024.173848
MLA:
Kashkarov, E. B., et al. "High temperature oxidation and thermal properties of laminated Ti3Al(Si)C2-TiC/Nb based composites obtained by spark plasma sintering." Journal of Alloys and Compounds 982 (2024).
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