Liu X, Yang B, Zhou X, Wu M, Spiecker E, Bachmann J, Hauke F, Hirsch A, Wei T (2023)
Publication Type: Journal article
Publication year: 2023
Three-dimensionally (3D) well-ordered and highly integrated graphene hybrid architectures are considered to be next-generation multifunctional graphene materials but still remain elusive. Here, we report the first realization of unprecedented 3D-patterned graphene nano-ensembles composed of a graphene monolayer, a tailor-made structured organophenyl layer, and three metal oxide films, providing the first example of such a hybrid nano-architecture. These spatially resolved and hierarchically structured quinary hybrids are generated via a two-dimensional (2D)-functionalization-mediated atomic layer deposition growth process, involving an initial lateral molecular programming of the graphene lattice via lithography-assisted 2D functionalization and a subsequent stepwise molecular assembly in these regions in the z-direction. Our breakthrough lays the foundation for the construction of emerging 3D-patterned graphene heterostructures.
APA:
Liu, X., Yang, B., Zhou, X., Wu, M., Spiecker, E., Bachmann, J.,... Wei, T. (2023). Synergistic Combination of Reductive Covalent Functionalization and Atomic Layer Deposition—Towards Spatially Defined Graphene-Organic-Inorganic Heterostructures. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202314183
MLA:
Liu, Xin, et al. "Synergistic Combination of Reductive Covalent Functionalization and Atomic Layer Deposition—Towards Spatially Defined Graphene-Organic-Inorganic Heterostructures." Angewandte Chemie International Edition (2023).
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