The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-

Izarova NV, Lin Z, Yang P, Kondinski A, Vankova N, Heine T, Kortz U (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 45

Pages Range: 2394-2398

Journal Issue: 6

DOI: 10.1039/c5dt04526f

Abstract

The polyoxo-22-palladate [Na2PdII22O12(As^VO4)15(As^VO3OH)]^25- (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd²⁺ and AsO4^3- ions in aqueous solution. Polyanion 1 comprises two {NaPd11} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd11} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.

Involved external institutions

Jacobs University Bremen gGmbH

Germany (DE)

How to cite

APA:

Izarova, N.V., Lin, Z., Yang, P., Kondinski, A., Vankova, N., Heine, T., & Kortz, U. (2016). The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-. Dalton Transactions, 45(6), 2394-2398. https://doi.org/10.1039/c5dt04526f

MLA:

Izarova, Natalya V., et al. "The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-." Dalton Transactions 45.6 (2016): 2394-2398.

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