Porphyrin-rylene-diimide-hexabenzocoronene triads

Martin M, Dusold C, Hirsch A, Jux N (2020)


Publication Type: Journal article

Publication year: 2020

Journal

DOI: 10.1142/S1088424619500810

Abstract

Hexa-peri-hexabenzocoronenes (HBCs), substituted by two different chromophores in an ortho arrangement, were synthesized for the first time and investigated towards their photophysical properties. Rylene-diimide dyes, in particular naphthalene-diimides (NDIs) and perylene-diimides (PDIs), were attached to the HBC as the first, and porphyrins as the second chromophore. Therefore, porphyrin-NDI-HPB as well as porphyrin-PDI-HPB precursors were accessed and converted into the respective HBC derivatives applying oxidative Scholl conditions. UV-vis absorption and fluorescence emission spectroscopy showed interesting photophysical behavior such as energy transfer processes. Particularly, the porphyrin-PDI-HBC displays pronounced absorption features between 330-650 nm, which cover a wide range of the visible spectrum.

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How to cite

APA:

Martin, M., Dusold, C., Hirsch, A., & Jux, N. (2020). Porphyrin-rylene-diimide-hexabenzocoronene triads. Journal of Porphyrins and Phthalocyanines. https://dx.doi.org/10.1142/S1088424619500810

MLA:

Martin, Max, et al. "Porphyrin-rylene-diimide-hexabenzocoronene triads." Journal of Porphyrins and Phthalocyanines (2020).

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