Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: From fundamentals to continuous production

Pizzutilo E, Kasian O, Choi CH, Cherevko S, Hutchings GJ, Mayrhofer K, Freakley SJ (2017)

Publication Status: Published

Publication Type: Journal article

Publication year: 2017

Journal

Chemical Physics Letters Elsevier

Publisher: ELSEVIER SCIENCE BV

Book Volume: 683

Pages Range: 436-442

DOI: 10.1016/j.cplett.2017.01.071

Abstract

The electrochemical synthesis of hydrogen peroxide (H2O2) represents a promising alternative to the anthraquinone process, as it combines on-site chemical and electrical production. The design of selective electrocatalysts is challenging and is commonly based on the alloying of elements to generate a synergistic effect and increase activity. In the present work, we report the electrochemical activity of Au-Pd nanoparticles immobilized directly onto an electrode as a model to study H2O2 electrochemical synthesis from fundamentals to continuous production. The impact of composition on the oxygen reduction reaction (ORR), the selectivity, as well as the peroxide reduction and oxidation reactions (PROR) are studied. (C) 2017 Elsevier B.V. All rights reserved.

Authors with CRIS profile

Karl Mayrhofer Lehrstuhl für Elektrokatalyse (HIERN)

Involved external institutions

Max-Planck-Institut für Eisenforschung GmbH (MPIE) / Max Planck Institute for Iron Research DE Germany (DE) Cardiff University GB United Kingdom (GB)

How to cite

APA:

Pizzutilo, E., Kasian, O., Choi, C.H., Cherevko, S., Hutchings, G.J., Mayrhofer, K., & Freakley, S.J. (2017). Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: From fundamentals to continuous production. Chemical Physics Letters, 683, 436-442. https://dx.doi.org/10.1016/j.cplett.2017.01.071

MLA:

Pizzutilo, Enrico, et al. "Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: From fundamentals to continuous production." Chemical Physics Letters 683 (2017): 436-442.

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