Building from Ga-Porphyrins: Synthesis of Ga-Acetylide Complexes Using Acetylenes and Polyynes
Walter V, Gao Y, Grzegorzek N, Krempe M, Hampel F, Jux N, Tykwinski R (2019)
Publication Type: Journal article
Publication year: 2019
Journal
Book Volume: 58
Pages Range: 494-498
Journal Issue: 2
Abstract
Multidimensional, conjugated building blocks have been formed through the axial coordination of polyynes to the central Ga atom of tetraarylporphyrins. Electron deficient pentafluorophenyl substituents in the meso-positions provide more stable σ-acetylide complexes to Ga than analogous structures with tert-butylphenyl groups. Mono-, di-, and triynes have been used, including a pyridyl endcapped diyne that allows for formation of porphyrin triads through coordination of the pyridyl ligand to a Ru porphyrin.
Authors with CRIS profile
Vroni Walter
Lehrstuhl für Organische Chemie I
Maximilian Krempe
Lehrstuhl für Organische Chemie I
Frank Hampel
Lehrstuhl für Organische Chemie I
Norbert Jux
Naturwissenschaftliche Fakultät
Rik Tykwinski
Lehrstuhl für Organische Chemie I
Involved external institutions
Canada (CA)How to cite
APA:
Walter, V., Gao, Y., Grzegorzek, N., Krempe, M., Hampel, F., Jux, N., & Tykwinski, R. (2019). Building from Ga-Porphyrins: Synthesis of Ga-Acetylide Complexes Using Acetylenes and Polyynes. Angewandte Chemie International Edition, 58(2), 494-498. https://dx.doi.org/10.1002/anie.201812142
MLA:
Walter, Vroni, et al. "Building from Ga-Porphyrins: Synthesis of Ga-Acetylide Complexes Using Acetylenes and Polyynes." Angewandte Chemie International Edition 58.2 (2019): 494-498.
BibTeX: Download