Inversion of donor-acceptor roles in photoinduced intervalence charge transfers

Aramburu-Trošelj BM, Oviedo PS, Ramírez-Wierzbicki I, Baraldo LM, Cadranel A (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Chemical Communications Royal Society of Chemistry

Book Volume: 55

Pages Range: 7659-7662

Journal Issue: 53

DOI: 10.1039/c9cc03483h

Abstract

Upon MLCT photoexcitation, {(tpy)Ru} becomes the electron acceptor in the mixed valence {(tpy^-)Ru^III-δ-NC-M^II+δ} moiety, reversing its role as the electron donor in the ground-state mixed valence analogue. Photoinduced mixed valence interactions can be tuned to obtain extended lifetimes and higher emission quantum yields, beneficial in supramolecular energy conversion schemes.

Authors with CRIS profile

Alejandro Cadranel Lehrstuhl für Physikalische Chemie I

Involved external institutions

Universidad de Buenos Aires (UBA) / University of Buenos Aires

Argentina (AR)

How to cite

APA:

Aramburu-Trošelj, B.M., Oviedo, P.S., Ramírez-Wierzbicki, I., Baraldo, L.M., & Cadranel, A. (2019). Inversion of donor-acceptor roles in photoinduced intervalence charge transfers. Chemical Communications, 55(53), 7659-7662. https://dx.doi.org/10.1039/c9cc03483h

MLA:

Aramburu-Trošelj, Bruno M., et al. "Inversion of donor-acceptor roles in photoinduced intervalence charge transfers." Chemical Communications 55.53 (2019): 7659-7662.

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