Europium and ytterbium complexes with o-iminoquinonato ligands: synthesis, structure, and magnetic behavior
Klementyeva SV, Lukoyanov AN, Afonin MY, Mörtel M, Smolentsev AI, Abramov PA, Starikova AA, Khusniyarov M, Konchenko SN (2019)
Publication Type: Journal article
Publication year: 2019
Journal
Book Volume: 48
Pages Range: 3338-3348
Journal Issue: 10
DOI: 10.1039/c8dt04849e
Abstract
Complexes of divalent ytterbium (1) and europium (2) with a dianionic o-amidophenolate ligand were prepared by both the direct reduction of 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzo-quinone (dpp-IQ) and the salt metathesis reaction of potassium o-amidophenolate with LnI(2) (Ln = Yb, Eu). Oxidation of o-amidophenolates 1, 2 with one equivalent of dpp-IQ as well as the salt metathesis reaction of potassium o-iminosemiquinolate with LnI(2) afforded ligand mixed-valent o-iminosemiquinonato-amidophenolato complexes of trivalent ytterbium (3) and europium (4). All novel complexes 1-4 were fully characterized, including the solid state structures of 1 and 2 determined by single crystal X-ray diffraction. The magnetic properties of paramagnetic 2-4 were examined.
Authors with CRIS profile
Max Mörtel
Lehrstuhl für Anorganische und Allgemeine Chemie
Marat Khusniyarov
Department Chemie und Pharmazie
Involved external institutions
Kazan (Volga region) Federal University / Казанский (Приволжский) федеральный университет
Russian Federation (RU)
Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS)
Russian Federation (RU)
Southern Federal University
Russian Federation (RU)
Russian Federation (RU)
Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS)
Russian Federation (RU)
Southern Federal University
Russian Federation (RU)
How to cite
APA:
Klementyeva, S.V., Lukoyanov, A.N., Afonin, M.Y., Mörtel, M., Smolentsev, A.I., Abramov, P.A.,... Konchenko, S.N. (2019). Europium and ytterbium complexes with o-iminoquinonato ligands: synthesis, structure, and magnetic behavior. Dalton Transactions, 48(10), 3338-3348. https://dx.doi.org/10.1039/c8dt04849e
MLA:
Klementyeva, Svetlana V., et al. "Europium and ytterbium complexes with o-iminoquinonato ligands: synthesis, structure, and magnetic behavior." Dalton Transactions 48.10 (2019): 3338-3348.
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